منابع مشابه
Reactivity of the dinuclear fulvalene cyclopentadienyl zirconium cationic species [{Zr(
The dinuclear cationic zirconium compound [{Zr( -C5H5)}2( -CH2)( -Cl)( -C5H4-C5H4)][BMe(C6F5)3] 1 reacts in dichloromethane at −78 °C with three equivalents of RNC (R= Bu, 2,6-Me2C6H3) via insertion into the Zr-methylene bond to give the new zirconium cationic species [{Zr( -C5H5)}2(Cl)(CNBu){ -[ -CN(Bu)-CH2-CN(Bu)}( -C5H4-C5H4)][BMe(C6F5)3] 2 and [{Zr( -C5H5)}2(Cl){CN(2,6-Me2C6H3)}[ -{CN(2,6-M...
متن کاملNovel Ti–Zr–Hf–Fe Nanostructured Alloy for Biomedical Applications
The synthesis and characterization of Ti40Zr20Hf20Fe20 (atom %) alloy, in the form of rods (f = 2 mm), prepared by arc-melting, and subsequent Cu mold suction casting, is presented. The microstructure, mechanical and corrosion properties, as well as in vitro biocompatibility of this alloy, are investigated. This material consists of a mixture of several nanocrystalline phases. It exhibits excel...
متن کاملSynthesis and characterisation of zirconium complexes for cell tracking with Zr-89 by positron emission tomography.
The increasing availability of the long half-life positron emitter Zr-89 (half life 78.4 h) suggests that it is a strong candidate for cell labelling and hence cell tracking using positron emission tomography. The aim was to produce a range of neutral ZrL4 lipophilic complexes for cell labelling which could be prepared under radiopharmaceutical conditions. This was achieved when the ligand was ...
متن کاملNew Zr II oscillator strengths and the zirconium conflict in the HgMn star χ Lupi
Lifetimes on the sub-nanosecond scale for the levels vD3/2, vF3/2 and vF5/2 in the 4d5s5p configuration in Zr II have been measured, using the method of laser-induced fluorescence. Combined with branching fractions obtained with the Lund Ultraviolet (UV) Fourier Transform Spectrometer (FTS), experimental oscillator strengths have been derived. From Hubble Space Telescope/Goddard High-Resolution...
متن کاملSolvent extraction and separation of hafnium from zirconium using Ionquest
industries, its nuclear properties in the pure metallic form make it highly desirable for nuclear applications. Zr is highly corrosion resistant and has a high melting point (2128 K) with a low thermal neutron absorption cross-section of Zr T = 0.18 b, which is significantly smaller than that of hafnium Hf T =115 b) (Speer, 1982), an element that coexists with Zr in nature. This makes Zr ideal ...
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ژورنال
عنوان ژورنال: Journal of Phase Equilibria and Diffusion
سال: 2007
ISSN: 1547-7037,1863-7345
DOI: 10.1007/s11669-007-9242-3